Madison Leads the Way
First Reverse-Osmosis System for Municipal Water Supply in Minnesota
From the Spring 1999 Waterline, the quarterly newsletter of the Minnesota Department of Health Public Water Supply Unit, © Waterline, Minnesota Department of Health
A
west-central Minnesota town of 1,900 that is the self-proclaimed Lutefisk
Capital of the World, the city of Madison has another distinction.
It is the site of the first reverse-osmosis treatment used in a municipal
water plant in the state.
History
Madisons first water system, built in 1913, pumped water directly
from a well into the distribution system. In response to complaints about
hardness, in 1939 the city constructed a lime softening plant that served
them for more than half a century. The lime-soda ash treatment process
did an adequate job of softening, but it wasnt removing the high
levels of naturally occurring sodium sulfates. Iron and manganese were
also a problem. These issues, combined with the realization that the
plant was nearing the end of its useful life and concerns about future
lime-sludge disposal efforts, made it apparent that a new facility was
needed with a number of issues to be considered in determining what type
of plant to construct. A primary consideration was the desire to continue
to reduce the hardness of the water supply, an amenity the townspeople
were accustomed to and would undoubtedly demand again.
Options
Lime softening and two membrane processesreverse-osmosis, and electrodialysis
reversalwere the options Madison looked at. Lime softening was
rejected because it would not meet all of the needs, while the high capital
cost of electrodialysis reversal caused the city to shy away from it.
That left reverse-osmosis as the frontrunner.
In the summer of 1994, a reverse-osmosis treatment process was pilot tested using one of the citys wells. The membrane was able to achieve an overall recovery rate of 75 percent during the testing period. The following year, Bolton & Menk, Inc. of Mankato, Minnesota, completed a pilot plant study using a bench-scale model of a reverse-osmosis unit. Brian DeWolf of Bolton & Menk said the study indicated success in reducing iron, manganese, sulfate, and total dissolved solids as well as hardness.
The decision was made to construct a reverse-osmosis plantwith a process consisting of aeration, detention, and filtrationalong with two new wells, a 300,000-gallon tower, and water mains to connect the new plant to the existing distribution system. The membrane treatment technology was selected in part because of its ability to eliminate the high chemical and labor costs and the lime-sludge problems associated with the existing treatment facility.
Construction began in March of 1997 and was completed by late summer in 1998. DeWolf says the reverse-osmosis process is a 7-4 system, meaning that it has seven first-pass membranes and four second-pass membranes. Water that doesnt make it through the membranes on the first pass is subject to the second-pass membranes, which increases the recovery rate, he explains. The recovery is about 75 percent, and the city blends about 35 percent filtered-only water with 65 percent reverse-osmosis water, so the overall plant efficiency is just over 80 percent.
The fact that only four of every five gallons entering the plant ends up going to the consumers is what DeWolf calls, one of the real drawbacks of a reverse-osmosis systema high level of rejection. However, he notes that since the plant went on-line, the water that makes it through the membranes is about 97 percent free of hardness, sulfate, sodium, and arsenic.
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Madison is the first municipal
water supply in Minnesota to use reverse-osmosis. |
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Treatment Process
Approximately 380 gallons per minute (gpm) are pumped from the wells.
The first stage of treatment is aeration to oxidize the iron and manganese,
an economical process that reduces chemical requirements and forms
a more filterable precipitate. Occasionally chlorine is added to assist
in the oxidation. Potassium permanganate is added to aid in the removal
of manganese before the water goes into the detention basin, which
is baffled to provide 30 minutes of oxidation. The basin has sludge
drawoff piping to aid in cleaning any settled solids from the bottom.
The settled solids are discharged into the sanitary sewer or the backwash
holding tank. Greensand filtration, which further reduces the manganese
level, is the next step in the treatment chain.
DeWolf says pretreatment is a key part of a reverse-osmosis plant. Removal of iron and manganese is critical to the reverse-osmosis process. Any amount of insoluble particles of iron and manganese can foul the membranes.
After the greensand filtration, the water enters the first clearwell and is then split with 80 gpm going to the second clearwell, to be used for blending with the finished reverse-osmosis water. The other 300 gpm goes into the reverse-osmosis unit, receiving hydrochloric acid on the way to lower the pH to 6.8. Sodium metabisulfate is sometimes added to remove any chlorine residual. An anti-scalant is also added.
Approximately 210 of the 300 gallons make it through the membraneseither on the first or second passwith approximately 90 gallons rejected to the storm sewer. The pH of the water that makes it through the membranes is raised to 7.2 with the addition of a caustic. It is then mixed with the filtered-only water in the second clearwell and pumped to the distribution system at 290 gpm as chlorine, fluoride, and a polyphosphate are added.
The plant cost of $1.5 million included both the gravity filtration for the pretreatment and the reverse-osmosis membranes as well as the electrical and control systems and the building itself. DeWolf estimates that, for this particular system, the addition of reverse-osmosis added approximately $300,000. The cost of the total projectincluding the new tower, wells, and mainswas approximately $2.9 million and was funded by a Rural Utilities Service loan from the U. S. Department of Agriculture of $2.3 and a grant from the Minnesota Department of Trade and Economic Development of $600,000.
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